Analysis of carbon monoxide production in methanol steam reforming reactor for generating hydrogen

: Seeking renewable energy sources has been a very important aspect in the development of human society, with many authors regarding hydrogen as a rather promising energy source. ere are several forms of obtaining hydrogen, including steam reforming of hydrocarbons, alcohols, and ethers. Some characteristics of methanol, such as processing at mild temperatures from 250 to 350oC under atmospheric pressure and production from biomass – no competition for food production – have distinguished it from other alcohols for steam reforming. e great disadvantage of this technology when applied in proton exchange membrane (PEM) fuel cells is that the process of methanol steam reforming involves not only hydrogen and carbon dioxide, but also the production of a small amount of carbon monoxide, which is suﬃcient to aﬀect the functionality of the fuel cells. is work presents the characterization of the catalyst HiFUEL R120 and shows how water/methanol molar ratio in the feed stream of an integral methanol steam reforming reactor inﬂuenced the conversion and the hydrogen selectivity in relation to carbon monoxide. is made it possible to identify the best operational conditions for lowering carbon monoxide content in the reactor eﬄuent, avoiding the use of a CO puriﬁcation unit.


Introduction
Hydrogen was proved to be a promising energy source (Armor, 1999;Mastalir et al., 2007;Lenzi et al., 2010) , especially when used for electrical energy generation in fuel cells.Fuel cells are electrochemical equipment that converts the chemical energy in fuels directly into electrical energy with high efficiency and Author notes gianeg@utfpr.edu.brlow environmental impact.By avoiding intermediate stages such as heat production and mechanical work, which are present in most typical energy generation methods, fuel cells present high performance in the conversion of chemical energy into electrical energy (30 to 40%).In this sense, they are better than energy generators that use internal combustion engines, 15 to 20% efficiency (Barlow, 1999;Trimm & Onsen, 2001;EG&G Technical Services, 2002;Avci, Önsan, & Trimm, 2003;Trimm, Adesina, & Cant, 2004).
A recent alternative is the use of methanol as the source of hydrogen.Methanol is a liquid with high hydrogen concentration (4 hydrogen atoms per carbon atom).is hydrogen can be made available through methanol steam reforming at relatively low temperatures (250 to 350 o C) and atmospheric pressure.In addition, methanol can be obtained from biomass (Hamelinck & Faaij, 2002;Hasegawa, Yokoyama, & Imou, 2010;Yang & Chan, 2011;Yong, Ooi, Chai, & Wu, 2013), presenting a simple and economical alternative (Farrauto et al., 2003).e equations for the methanol steam reforming reaction and the reverse water gas shi reaction, as well as their respective enthalpies, are listed below (Purnama et al., 2004) Equation 1 and 2: (1) (2) Carbon monoxide is an unwelcome by-product of methanol steam reforming.erefore, several processes of H 2 purification are used to decrease the amount of CO contaminating the hydrogen that feeds a fuel cell and the effects of said CO.According to the literature (Narusawa, Hayashida, Kamiya, & Roppongi, 2003), the maximum allowed CO content is 50 ppm.erefore, when integrating a fuel cell to a reforming reactor, maintaining acceptable levels of CO concentration in the reforming reactor effluent is a great challenge.Previous studies indicate that an increase in the amount of water combined with the methanol fed to the reactor decreases the resulting amount of carbon monoxide (Breen & Ross, 1999;Agrell, Birgersson, & Boutonnet, 2002;Lee, Ko, & Kim, 2004).Agrell et al. (2002) observed an increase in selectivity resulting from water/methanol molar ratio variation from 1.0 to 1.3.However, the authors did not assess the implications of the increased water content on conversion and composition of the reactor effluent stream.Despite a great number of studies on methanol steam reforming, the literature presents limited information on the operational conditions of the commercial catalyst HiFUEL R120.In this context, the proposal of this study was to characterize the commercial catalyst and to assess the use of water as a CO suppression agent, which is notably interesting for the production of H 2 through methanol steam reforming, as low CO concentrations in the reactor effluent stream enable the direct feeding of PEM fuel cells, avoiding purification steps.

Experimental
Catalyst e commercial catalyst HiFUEL R120 produced by Alfa Aesar was used for the methanol steam reforming tests.HiFUEL R120 is a copper-based mass catalyst.Its properties are described in Table 1.

Specific surface area (B.E.T. analysis)
Porous properties such as specific surface area, mean pore diameter, and pore volume were determined using a Nova-1200 Quantachrome analyzer with N2 adsorption at -196,15ºC.To conduct this analysis, the whole pellet catalyst was used.Before the analysis, the samples were submitted to thermal treatment at 300ºC under vacuum for 8 hours to eliminate any existing water within the pores of the solids.

Temperature programmed reduction (TPR)
e measurements were conducted using a home-built TPR apparatus and a quartz tube with the catalyst sample.e samples (0.019 g) were heated from room temperature to 1000ºC at a heating rate of 10ºC min.-1and a gas flow rate of 20 mL min. - (1.75% H 2 /98.25%Ar).e thermocouple was located in the central position of the bed.

X-ray diffraction
XRD measurements were performed using a D8 Advance BRUKER diffractometer with Cu-Kα radiation (λ = 1.5406Å) at 40 kV and 40 mA.e obtained diffractograms were compared with diffraction patterns from the Joint Committee on Powder Diffraction Standards (JCPDS, 2003).

ermogravimetric analysis (TGA)
A Shimadzu TGA-50 ermogravimetric Analyzer was used to analyze a 10 mg catalyst sample at a heating rate of 10°C min -1 from room temperature to 800°C, under an inert gas flow (nitrogen) of 20 mL min -1 .Characteristics of the catalyst HiFUEL R120.

Reaction Parameters.
Although stoichiometry suggests that a single mole of water per mole of methanol is required, excess steam should be used to reduce by-product carbon formation.Temperature was monitored at various catalyst bed locations using a multipoint thermocouple (Termopa Industrial Ltda), which is a 3 mm OD, 70 cm long stainless steel tube containing 11 thin type K thermocouples whose tips were spaced by 3 cm.In the inlet and outlet portions of the reactor, inert alumina spheres were used to homogenize the gaseous mixture.Aer being properly vaporized at 200 o C in the preheater, the ethanol-water mixture entered the reactor inside an electric furnace [E].e gases from the reactor (H 2 , CO 2 , H 2 O, CO, CH 3 OH) passed through a condenser [F] and a phase separator [G], from which the liquid product (CH 3 OH and H 2 O) was collected and the gas stream (H 2 , CO 2 , and CO) was submitted to chromatographic analysis [H].e experimental tests were conducted as follows: aer charging the integral reactor with 26.5 g of catalyst HiFUEL R120, it was activated with hydrogen and a long-term experiment was carried out in order to avoid the conclusion of the tests at the initial catalyst deactivation period.e total reaction time was 100 hours.Aer the catalyst was proved to be stable for conversion through chromatographic analyses -as reported in literature (Rostrup-Nielsen, 1997) -several tests were carried out at different operational conditions -Table 2. e products were continuously analyzed using on-line gas chromatography (ermo Finnigan Trace GC-2000 equipped with thermal conductivity detector and two combined packed columns -Porapaq ® -N and 13X molecularsieve).e samples were automatically injected in the chromatograph using a 10-port gas-sampling valve (VICCI Valco).e parameters used to quantify the reactor performance (conversion and selectivity) are defined in Equation 3 and 4, in which F CO2 and F CO stand for the molar flow rate of carbon dioxide and carbon monoxide, respectively, at the reactor outlet.F CH3OH is the molar flow rate of methanol at the reactor inlet.C H2 and C CO represent the molar concentrations of hydrogen and carbon monoxide, respectively, at the reactor outlet., which enables the reagents to access active sites in the catalytically active surface.e mean pore diameter is favorable for this reaction, since the average pore distribution is 4.3 Å and the effective diameter of the methanol molecule is 4.2 Å -slightly lower (Perera, Sokolic, & Zoranic, 2007).e value found for specific pore volume was 0.08 cm 3 g -1 .e temperature programmed reduction (TPR) profile of HiFUEL R120 (CuO/ZnO/Al 2 O 3 ) (Figure 2A) shows a peak in the 200-300 o C region.Some authors (Shishido et al., 2006;Yong et al., 2013) reported a gradual reduction of CuO as a shoulder around 200 o C, followed by a clear reduction peak around 240 o C. ZnO-rich samples revealed a weak peak around 220 o C, with the addition of Cu.Subsequently, a new peak appeared around 240 o C, when Cu/Zn ratio exceeded 50/50.Fierro et al. (1996) reported that Cu/ ZnO/Al 2 O 3 calcined at 400 o C for 4 hours presented a single reduction peak centered at 223 o C, which was assigned to the reduction of CuO to Cu. e hydrogen consumption between 400 and 700°C (Figure 2) could be attributed to Cu-Zn/Cu-Al interactions.
e thermogravimetric analysis of catalyst HiFUEL R120 (Figure 3A) has shown, in its TGA/DTGA profiles, mass loss from room temperature to 800°C, reaching around 20%. e weak peak at around 100°C was attributed to the physically adsorbed water (He, Cheng, Liang, Yu, & Zhao, 2013), while the peak between 100 and 200°C was attributed to structural water (Fu, Bao, Ding, Chou, & Li, 2011;He et al., 2013).Moreover, the peak at 240ºC could be related to the decomposition of Zn 4 Al 2 (OH) 12 (CO 3 ).3H 2 O and subsequent liberation of compounds such as carbon dioxide and water.From 600 to 800°C, one could attribute the occurrence of gradual mass loss to the continuous release of residual bonding components resulting from the thermal decomposition of organic species.

Catalytic tests
rough the assessment of the different water/methanol molar ratios at 250°C, the results indicated a slight variation in conversion -between 5 and 7% (Figure 4A).As for the mole fractions, a slight decrease was observed for CO and H 2 with increasing water/methanol molar ratios, along with a small increase in CO 2 mole fraction.e decrease in the H 2 mole fraction was possibly a result of the lower methanol concentration feeding the reactor.Figure 4B illustrates that, as the reaction temperature was increased to 300°C, the conversion for molar ratios of 1.0 and 3.5 were of 13 and 23%, respectively.e hydrogen mole fraction presented a mild decrease, while CO dropped from 0.58 (molar ratio of 0.8) to 0.28% (molar ratio of 3.5).An increase in the CO 2 mole fraction is also shown.As expected, the highest conversions were obtained at 350°C, since the methanol steam reforming reaction is endothermic, increasing as molar ratio is increasedthe lowest being 32 (molar ratio 1.0) and the highest being 51% (molar ratio 3.5), according to Figure 4A.is emphasizes the influence of temperature and molar ratio on the methanol steam reforming reaction.e hydrogen mole fraction presented a mild decrease while that of CO presented a more significant decrease, dropping from 1.45 (molar ratio 0.8) to 0.34% (molar ratio 3.5) at 350 o C. e CO 2 mole fraction, on the other hand, increased with increasing molar ratio.
As for selectivity, Figure 5B shows that for all temperatures it increased as the water/methanol molar ratio in the solution fed to the reactor was increased up to 2.5.Above this level, the value became virtually stable.e increase in selectivity was sharper at 250ºC.It is also clear from Fig. 5B that selectivity decreases with increasing temperature.A higher temperature leads to a higher conversion, but it also favors the formation of CO. is increase in CO suggests that the reverse water gas shi reaction, which is endothermic, occurs simultaneously.Figure 6A shows that an increase in temperature favors conversion.Maximum conversion was obtained at 350ºC with a feed molar ratio of 3.5.Mole fractions of the products and methanol conversion at 250ºC (A) and Mole fractions of the products and methanol conversion at 300ºC (B).Methanol conversion dependence on temperature and feed molar ratio (A) and Dependence of CO concentration in the hydrogen stream on temperature and feed molar ratio (B).
It is evident in Figure 6B that CO concentration depends on temperature and feed molar ratio.High temperatures favor CO production, since the reverse water gas shi reaction is exothermic.However, when the water/methanol molar ratio is higher than 2.5, the formation of CO is suppressed.is enables the attachment of a methanol steam reforming reactor to a fuel cell without any intermediate purification stages for CO removal.e fitting of the experimental data on CO concentration (C CO ), temperature (T), and feed molar ratio (RM) to an equation like Equation 5 helps in decision making for the operation of a fuel cell.Equation 5 was adjusted from the experimental data presented in Figure 6B using code poly25, available for MATLAB ® .
(5) By analyzing the experimental data, it is possible to state that a methanol steam reforming reactor can produce a hydrogen-rich stream with CO content lower than 50 ppm, enabling the reactor to be attached to a fuel cell without any purification stages.Still, at 300ºC and molar ratio of 3.5, the reactor does not reach a high conversion, which would imply further steps to separate the residual methanol, possibly through condensation, followed by re-feeding to the reactor, according to theoretical conclusions in a previous work (Menechini Neto, Santos, & Jorge, 2014).

Conclusion
e obtained results indicate that the water/methanol molar ratio has significant influence on CO production in methanol steam reforming, showing water to be a suppressant of CO in the process.e results point to a sharp increase in selectivity at molar ratios between 0.8 and 2.0, while in the interval from 2.0 to 3.5 the increase is minor.Considering the obtained results, it would be possible to generate a 420 mL min -1 stream with a CO content of 41 ppm, able to operate a 30 W fuel cell, using a reactor at 300ºC and methanol/water feed molar ratio of 2.5.

Figure 1
Figure 1 is an illustration of the module used for all reaction tests.e solution of methanol (Nuclear) and water was stored in a graduated cylinder [A], so that the inlet flow rate could be assessed.e water used for steam generation had received prior treatment according to standard procedures.A peristaltic pump [B] took the solution (CH 3 OH/H 2 O) to the preheater [C], where it might or might not join the gases from the cylinders [D].Nitrogen (N 2 ) and Hydrogen (H 2 ) used in the catalytic tests had over 99.9% purity (White Martins/Praxair).Steam reforming reaction was carried out under atmospheric pressure using a tubular fixed-bed stainless steel reactor -0.0127 m internal diameter, 0.70 m long.e feed stream composition included methanol and deionized water according to reaction parameters listed in Table2.
XML JATS4R by Redalyc Project academic non-profit, developed under the open access initiative Results and discussion Characterization B.E.T. analyses indicate that the catalyst HiFUEL R120 has a surface area of 75 m 2 g cat -1

FIGURE 2 .
FIGURE 2. TPR profile of the commercial catalyst HiFUEL R120 (A) and Typical s-TPR profiles of HiFUEL R120.(a) First TPR; (b) second TPR aer N 2 O oxidation at 60ºC (B).

FIGURE 5 .
FIGURE 5. Mole fractions of the products and methanol conversion at 350 o C (A) and Selectivity dependence on temperature and feed molar ratio (B).